UN 1860: VINYL FLUORIDE, STABILIZED

UN 1860 (VINYL FLUORIDE, STABILIZED) belongs to ADR class 2 (Gases). Hazard identification number: 239. Tunnel restriction code: B/D.

Class
2Gases
Classification code
2F
Warning labels
2.1
Hazard identification number (Kemler)The first digit is the main hazard (2 gas, 3 flammable liquid, 4 flammable solid, 5 oxidising, 6 toxic, 8 corrosive, 9 miscellaneous), the next digits are additional hazards, a repeated digit (e.g. 33) means an intensified hazard, an X before the number means a dangerous reaction with water.
239
Tunnel restriction code
B/D: Code with a slash: the restriction depends on the way of carriage (in a tank or otherwise). See table 8.6.4 of ADR. Tunnel categories in the code: B, D.
Transport categoryThe transport category (0 to 4) sets the multiplier: according to ADR Check, category 1: multiplier 50, category 2: multiplier 3, category 3: multiplier 1, category 4: multiplier 0 (no limit), and category 0 means the exemption does not apply. Points are the net quantity (kg or L) times the multiplier.
2
Multiplier for the 1000-point limitPoints are the net quantity (kg or L) times the multiplier; a load total not exceeding 1000 points falls within the ADR 1.1.3.6 exemption.
3
Limited quantity (LQ)The largest quantity per inner packaging for which carriage can use the limited-quantity rules.
0
Excepted quantity (EQ)A code indicating the limits for excepted quantities; its content is given in the text of ADR.
E0
Packing instructionsPacking instruction codes (e.g. P, IBC, R) indicate which packagings are permitted.
P200
Mixed packingCodes (MP) say how this substance may be packed together with others in one outer packaging.
MP9
Carriage: packagesThe codes indicate provisions on carriage, loading and unloading.
V8
Loading, unloading and handlingThe codes indicate provisions on carriage, loading and unloading.
CV9, CV10, CV36
Operation of the vehicleCodes (e.g. S2, S20) indicate additional operating provisions for carriage.
S2, S4, S20

The content of the packing codes and the carriage provisions is in ADR, chapters 4.1 and 7.

Special provisions

  • 386: When substances are stabilized by temperature control, the provisions of 2.2.41.1.21, 7.1.7, special provision V8 of Chapter 7.2, special provision S4 of Chapter 8.5 and the requirements of Chapter 9.6 apply.
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    When chemical stabilization is employed, the person offering the packaging, IBC or tank for carriage shall ensure that the level of stabilization is sufficient to prevent the substance in the packaging, IBC or tank from dangerous polymerization at a bulk mean temperature of 50 °C, or, in the case of a portable tank, 45 °C. Where chemical stabilization becomes ineffective at lower temperatures within the anticipated duration of carriage, temperature control is required. In making this determination factors to be taken into consideration include, but are not limited to, the capacity and geometry of the packaging, IBC or tank and the effect of any insulation present, the temperature of the substance when offered for carriage, the duration of the journey and the ambient temperature conditions typically encountered in the journey (considering also the season of year), the effectiveness and other properties of the stabilizer employed, applicable operational controls imposed by regulation (e.g. requirements to protect from sources of heat, including other cargo carried at a temperature above ambient) and any other relevant factors.
  • 662: Cylinders not conforming to the provisions of Chapter 6.2 which are used exclusively on board a ship or aircraft, may be carried for the purpose of filling or inspection and subsequent return, provided the cylinders are designed and constructed in accordance with a standard recognized by the competent authority of the…
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    country of approval and all the other relevant requirements of ADR are met including: (a) The cylinders shall be carried with valve protection in conformity with 4.1.6.8; (b) The cylinders shall be marked and labelled in conformity with 5.2.1 and 5.2.2; and (c) All the relevant filling requirements of packing instruction P200 of 4.1.4.1 shall be complied with. The transport document shall include the following statement: "Carriage in accordance with special provision 662".
  • 676: For the carriage of packages containing polymerizing substances the provisions of special provision 386, in conjunction with 7.1.7.3, 7.1.7.4, 5.4.1.1.15 and 5.4.1.2.3.1, need not be applied, when carried for disposal or recycling provided the following conditions are met:
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    (a) Before loading an examination has shown that there is no significant deviation between the outside temperature of the package and the ambient temperature; (b) The carriage is effected within a period of not more than 24 hours from that examination; (c) The packages are protected from direct sunlight and from the impact of other sources of heat (e.g. additional loads that are being carried above ambient temperature) during carriage; (d) The ambient temperatures during the carriage are below 45 °C; (e) Vehicles and containers are adequately ventilated; (f) The substances are packed in packages with a maximum capacity of 1000 litres. In assessing the substances for carriage under the conditions of this special provision, additional measures to prevent dangerous polymerization may be considered, for example the addition of inhibitors.

Tools

Limited quantities (LQ) · 1000-point calculator · Load compatibility

Data: ADR Check (adr.exportsy.pl). Basis: European Agreement concerning the International Carriage of Dangerous Goods by Road (ADR). For guidance only, it does not replace the text of the Agreement or the assessment of a dangerous goods safety adviser (DGSA).